| 第 31 卷第 5 期 |  | Vol. 31 No. 5 | | 2001 年 10 月 | Oct 2001 |
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所属栏目：其它
邻硝基苯甲醛合成工艺研究 |
| 田澍; 魏运洋(南通师范学院; 南京理工大学化工学院; 江苏南通; 江苏南京) |
| 摘 要：以邻硝基苯甲醇为原料 ,经铜胺配合物催化氧化得目标产物。合成的工艺条件为 :氧化剂摩尔比 ,n (对硝基苯甲醇 )∶n (CuCl)∶n (邻菲咯啉 )∶n (肼二甲酸二乙酯 )∶n(K2 CO3) =1∶0 .0 5∶0 .0 5∶0 .0 5∶2 ,氧化温度 78～ 82℃ ,氧化时间 3h。邻硝基苯甲醛收率为74 1%。催化剂可回收经简单处理后重复利用 |
| 关键词：邻硝基苯甲醇; 催化; 氧化; 邻硝基苯甲醛; 催化剂回收 |
| 中图分类号：TQ246.1+5 文献标识码：A 文章编号：1009-9212(2001)05-0016-02 |
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| Synthesis of Nitrobenzaldehydes |
| TIAN Shu 1; WEI Yun-yang 2 （1 Nantong teachers college; nantong 226007 China; 2. School of Chemical engineering; Nanjing University of Science & Technology; Nanjing 210094; China） |
| Abstract：2 Nitrobenzyl alcohols were oxidized to 2 nitrobenzaldehydes via copper catalyzed air oxidation. This represents a new and facile route to the nitrobenzaldehydes. Optimum reaction conditions were as follow: the oxidition molar ratio of nitrobenzaldechol∶CuCl∶DEAD∶o phenanthroline∶K 2CO 3 was 1∶0.05∶0.05∶2, reaction temperature 78～82℃, reaction time 3 h. The overall yield of 2 nitrobenzaldehyde was 74.1%. And the catalyst can be recycled. |
| Key words：2 Nirobenzyl alcohols; catalysis; oxidation; 2 nitrobenzaldehyde |
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收稿日期：2001-05-08
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