| 第 41 卷第 1 期 |  | Vol. 41 No. 1 | | 2011 年 2 月 | Feb 2011 |
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所属栏目：功能材料
木质素-硅藻土复合物在三角带底胶中的应用研究 |
| 曹仲林1，吴芳梅1，宋青霞1，廖泽栋1，何家龙2，苏胜培1*
（1. 湖南师范大学 化学化工学院，资源精细化与先进材料湖南省高校重点实验室，湖南 长沙 410081；2. 醴陵市橡胶制品厂，湖南 醴陵412200） |
| 摘 要：通过共沉淀-脱水法制备了木质素-硅藻土复合物填料，并湿法混炼制备了木质素-硅藻土复合物填充三角带底胶实验胶。通过无转子硫化仪、电子万能试验机、邵氏硬度计研究了硫磺和促进剂的量、天然橡胶和顺丁橡胶的量对三角带底胶实验胶的硫化特性和力学性能的影响，并将木质素-硅藻土复合物填充三角带底胶与炭黑填充的三角带底胶实验胶进行了比较。结果表明：增加硫磺和促进剂的量，提高了三角带底胶实验胶的硬度和300%定伸应力；将顺丁橡胶替换成天然橡胶则提高了三角带底胶实验胶的拉伸强度。配方调整后三角带底胶实验胶的综合性能已与N330填充胶料相当。 |
| 关键词：三角带底胶；木质素-硅藻土复合物填料；硫化特性；力学性能 |
| 中图分类号：TQ333 文献标识码：B 文章编号：1009-9212（2011）01-0049-04 |
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| Study on Application of Lignin-diatomite Complex in Base Rubber of V-Belt |
| CAO Zhong-lin1，WU Fang-mei1，SONG Qing-xia1，LIAO Ze-dong1，HE Jia-long2，SU Sheng-pei1*
（1. College of Chemistry and Chemical Engineering, The key Laboratory of Meticulous Resource and Advanced Materials, Hunan Normal University, Changsha 410081, China; 2. Liling rubber produce factory, Liling 412200, China） |
| Abstract：A novel rubber filler, lignin-diatomite complex, was prepared by co-precipitation and dehydration of the mixture of black liquor and diatomite and used in the base rubber of V-belt manufactured by mechanical mixing method. The effect of the content of sulphur and accelerator, the mass of natural rubber （NR） and cis-1，4-polybutadiene rubber （BR） on the curing characteristics and the mechanical properties of the base rubber of V-belt were studied. The base rubber filled with lignin- diatomite complex was compared with that filled with carbon black. The experiments showed that the Shore A hardness and 300% modulus of the base rubber were increased as the content of sulphur and accelerator increased, and the tensile strength of the base rubber was increased when BR was replaced with NR. After some adjustments of the formulation, the comprehensive properties of the base rubber filled with lignin-diatomite were similar to those of the base rubber filled with carbon black. |
| Key words：base rubber of V-belt；lignin-diatomite complex；curing characteristic； mechanical property |
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基金项目：湖南师范大学潇湘学者启动资金资助课题（化050613）。
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作者简介：曹仲林（1986-），男，湖南常宁人，硕士研究生，研究方向：高分子复合材料。（E-mail： zhonglincao@126.com）
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联 系 人： 苏胜培，教授，博士生导师，研究方向：高分子复合材料。（E-mail：sushengpei@gmail.corn）
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收稿日期：2011-02-16
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