| 第 32 卷第 2 期 |  | Vol. 32 No. 2 | | 2002 年 4 月 | Apr 2002 |
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所属栏目：其它
对叔丁基苯酚催化加氢制备顺式对叔丁基环己醇 |
| 熊前政; 刘智凌; 廖文文; 王晓光; 刘列琼(湖南化工研究院; 湖北沙隆达集团煤化公司催化剂厂; 湖南长沙) |
| 摘 要：采用雷尼镍、Pd/C、Pt/C等为催化剂 ,由对叔丁基酚液相催化加氢合成顺式对叔丁基环己醇。在反应温度 110～ 130℃ ,反应压力 5MPa条件下 ,对叔丁基酚转化率 10 0 % ,对叔丁基环己醇收率 >98% ,顺式对叔丁基环己醇选择性 >75 % |
| 关键词：对叔丁基苯酚; 对叔丁基环己醇; 催化; 加氢 |
| 中图分类号：TQ233 文献标识码：A 文章编号：1009-9212(2002)02-0025-02 |
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| The synthesis of cis-4-Tert-butylcyclohexanol from 4-Tert-butylphenol by Catalytic hydrogenation. |
| Xiong Qian Zheng; et al（Hunan Research Institute of Chemical Industry; Changsha 410007; China）. |
| Abstract：The synthesis of cis 4 tert butylcyclohexanol was studied from 4 tert butylphenol with Ni,Pd/C,Pt/C et al as catalyst by the way of liquid catalytic hydrogenation.The optimun technology Condition were that the reactic temperature was 110～130℃,the reactic pressure was 1～5MPa.The conversion of 4 tert butylphenol was 100%,The yield of 4 tert butylphenolohexanol was over 98%,The selectivity of cis 4 butylcyclohexanol was over 75%. |
| Key words：tert butylcyclohexanol; catalysis hydrogenation |
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收稿日期：2001-11-27
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