| 第 46 卷第 5 期 |  | Vol. 46 No. 5 | | 2016 年 10 月 | Oct 2016 |
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所属栏目：染料、颜料及涂料
有机氟硅改性苯丙乳液的合成及疏水性能 |
| 牟玉兰1，2，夏 伟1，郑大锋1，曹维良1
（1． 海南科技职业学院，海南 海口 571126；2． 江西理工大学，江西 赣州 341099） |
| 摘 要：采用连续乳液聚合法合成了有机氟硅改性苯丙乳液，研究了乳化剂、MBFA-12、DB-151用量对乳液稳定性的影响。结果显示，乳化剂用量为0.8%~1.0%（m／m），m（MBFA-12）∶m（DB-151）=1∶1，用量各为4 g时，合成的氟硅改性苯丙乳液具有良好的稳定性。其涂层与水的接触角为128.5°，具有超疏水性。合成的氟硅改性苯丙乳液在建筑防水涂料、油水分离等领域中具有一定应用前景。 |
| 关键词：改性苯丙乳液；有机氟；有机硅；接触角；疏水性 |
| 中图分类号：TQ630.4 文献标识码：A 文章编号：1009-9212（2016）05-0030-03 |
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| Styrene-acrylic Emulsion Modified by Organic Fluoride and Silicone and Its Hydrophobic Property |
| MOU Yu-lan1,2, XIA Wei1, ZHENG Da-feng1, CAO Wei-liang1
(1. School of Biochemical Chemical Engineering, Hainan Institute of Science and Technology, Haikou 571126, China; 2. Jiangxi university of science and technology, Ganzhou 341099, China) |
| Abstract：In order to increase the hydrophobic property of the styrene-acrylic emulsion, styrene-acrylic emulsion modified using organic fluoride and silicone was synthesized through continuous emulsion polymerization. The effect of the loading of emulsifier, MBFA-12 and DB-151 on the emulsion stability was studied. The results showed that, when the amount of emulsifier was 0.8%~1.0%, the usage of both MBFA-12 and DB-151 was 4 g, the average size of the emulsion was smaller while the modified emulsion was more stable. The contact angle between emulsion film and water was 128.5°, showing that the film had super hydrophobility. The modified styrene-acrylic emulsion had promising application in the field of waterproof coating and oil-water separation. |
| Key words：modified styrene-acrylic emulsion; organic fluorine; organic silicon; contact angle; hydrophobic property |
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基金项目：海南省自然科学基金资助（20155202）。
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作者简介：牟玉兰（1985-），女，四川达州人，硕士研究生，讲师，主要从事高分子乳液的合成与应用（E-mail：407484467@qq.com）。
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收稿日期： 2016-09-2
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