| 第 32 卷第 4 期 |  | Vol. 32 No. 4 | | 2002 年 8 月 | Aug 2002 |
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所属栏目：其它
三苯基膦合成工艺改进 |
| 高荣; 蔡春; 吕春绪(南京理工大学化工学院; 江苏南京; 210094) |
| 摘 要：采用弗 克法 ,以苯 ,三氯化磷 ,硫磺直接回流反应 ,生成三苯基硫膦 ,再经锌粉还原制得三苯基膦。其中采用不分离出三苯基硫膦以及用锌粉作还原剂等新工艺。该法具有收率高 ,产品纯 ,反应条件缓和等特点。 |
| 关键词：三苯基膦; 合成; 三苯基硫膦 |
| 中图分类号：TQ265.1 文献标识码：B 文章编号：1009-9212(2002)04-0053-02 |
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| Improvement on the New Synthetic Procedure of Tripenyl-phosphine |
| GAO rong; CAI chun; LU Chun xu（Chemical Engineering School; Nanjing University of Science and Technology; Nanjing; 210094; China） |
| Abstract：An "one pot" method to synthesize triphenylphosphine was found from the reduction by zinc of triphenylphosphine sulfide,which was prepared directly from benzene by reacting it with sulfur and phosphorus trichloride with high yield,pure product and moderate conditions. |
| Key words：triphenylphosphine; synthesis; triphenylphosphine sulfide |
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收稿日期：2002-06-20
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