第 47 卷第 6 期 Vol. 47 No. 6 2017 年 12 月 Dec 2017

所属栏目：功能材料 聚苯乙烯酚醛吸附树脂的合成及对水中苯酚的吸附性能

粟 琴，龙 宇，廖慧玲，钟世华* （湖南师范大学 化学化工学院，资源精细化与先进材料湖南省高校重点实验室，石化新材料与资源精细利用国家地方联合工程实验室，湖南 长沙 410081）

摘　要：用氯甲基化聚苯乙烯分别与2-萘酚和 S-联萘酚反应，制成了以聚苯乙烯为基质的酚羟基修饰的PS-N树脂和PS-SD树脂，用静态和动态方法研究了PS-N树脂和PS-SD树脂的吸附行为，研究发现：两种树脂对苯酚的吸附都为放热吸附，主要为氢键吸附。与PS-N树脂相比，PS-SD树脂具有更大的比表面积，对苯酚的吸附量明显大于PS-N树脂，有更好的应用前景。

关键词：酚醛树脂；氯甲基化聚苯乙烯；2-萘酚；S-联萘酚；吸附

中图分类号：TQ325　　文献标识码：A　　文章编号：1009-9212（2017）06-0046-04

Synthesis of Polystyrene Phenol Formaldehyde Resin and Its Adsorption Property for Phenol

SU Qin, LONG Yu, LIAO Hui-lin, ZHONG Shi-hua* (College of Chemistry and Chemical Engineering, Hunan Normal University, Key Laboratory of Fine Resources and Advanced Materials of Hunan Province, National & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Changsha 410081, China)

Abstract：The PS-N and PS-SD resins based on polystyrene were synthesized through the reaction of chloromethylated polystyrene with 2-naphthol and(S)-BINOL. The adsorption behaviors of resins were studied under static and dymanic conditions. The results were compared and found that the adsorption of phenol was an exothermic process and affected by hydrogen bonding interactions. The PS-SD showed a larger surface area and higher adsorption ability for phenol, and PS-SD resin was promising application in industry.

Key words：phenolic resin; chloromethylated polystyrene; 2-hydroxynaphthalene; (S)-BINOL; adsorption

基金项目：湖南校企合作创新创业教育基地（湘教通（2016）394号）。

作者简介：粟 琴（1993-），女，湖南常德人，硕士研究生，主要从事有机化学研究（E-mail：771576515@qq.com）。

联 系 人：钟世华，教授，博士，从事功能高分子的合成与天然产物分离（E-mail：zhongshihua@hunnu.edu.cn）。

收稿日期：2017-12-01