| 第 32 卷第 4 期 |  | Vol. 32 No. 4 | | 2002 年 8 月 | Aug 2002 |
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所属栏目：其它
水扬酸镍的合成表征及结构分析 |
| 刘卫兵; 李良超(楚源集团华丽染料公司; 荆州师范学院化学系; 湖北石首; 434400; 湖北荆州; 434100) |
| 摘 要：用流变相反应法合成了Ni(OH)Sal·H2 O和Ni2 (OH) 2 Sal2 ·H2 O。通过元素分析、TG、IR、XRD和磁矩对其结构进行了分析。结果表明两个配合物都属于单斜晶系 ,其晶胞参数为 ,Ni(OH)Sal·H2 O∶a =13.1179,b =11.36 41,c =9.5 6 0 5 ,β =92 .96 2 ,V =14 2 3.31(97) 3,Z =7,Dcalcd .=1.885 g/cm3,Dexpt=1.85 8g/cm3;Ni2 (OH) 2 Sal2 ·H2 O :a =13.12 17,b =11.35 80 ,c =9.5 5 2 2 ,β =92 .978 ,V =14 2 1.72 (95 ) 3,Z =4 ,Dcalc=2 .0 73g/cm3,Dexp=2 .0 0 0 g/cm3。 |
| 关键词：水杨酸镍; 流变态; 合成; 结构分析 |
| 中图分类号：o614.4 文献标识码：A 文章编号：1009-9212(2002)04-0044-02 |
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| The Rheological State Synthesis and Characterization And Structural Analysis of Nickel Monosalicylates |
| LIU Wei bing; LI Liang chao.（Depart.of Chem.; Jingzhou Normal College; Hubei Jingzhou; 434100; China） |
| Abstract：Nickel monosalicylates [Ni(OH)(C 6H 4OHCO 2)·H 2O(A) and Ni 2(OH) 2(C 6H 4OHCO 2) 2·H 2O(B)] were synthesized through the rheological phase reaction method.Their structure was characterized by elemental analysis,IR,TG,X ray power diffraction and magnetic moment.XRD indicated that the two complexs are monoclinic crystal system and its crystal cell parameters are respectively,(A)∶a=13.1179,b=11.3634,c=9.5605?,β=92.962,V=1423.31(97)? 3,Z=9,D calcd =1.885g/cm 3,(B)∶a=13.1217,b=11.3580,c=9.552... |
| Key words：nickel salicylates; rheological phase; synthesis; structure analysis |
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基金项目：湖北省教育厅自然科学基金资助课题(99C069)
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收稿日期：2002-07-20
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