第 48 卷第 4 期 Vol. 48 No. 4 2018 年 8 月 Aug 2018

所属栏目：医药及中间体 一种新型苯并咪唑衍生物及其锌配合物的合成与表征

刘 鸿1，谢葆华2 （1. 惠州学院 化学与材料工程学院，广东 惠州 516007；2.惠州学院 财务处，广东 惠州 516007）

摘　要：以水杨酸、邻苯二胺及一溴辛烷为原料，制备了1-辛基-2-（2-羟基苯基）苯并咪唑（L）及其锌配合物（I），并用IR、UV、1H NMR、元素分析等对其结构和性能进行表征，测定了L和I的荧光性，它们的最大荧光发射波长分别为392 nm、450 nm和412 nm，测定了I的晶体结构，为单斜晶系，空间群C2／c，a=30.4244（15）?魡，b=9.7944（4）?魡，c=17.896（1）?魡，V=5296.6（5）?魡3，Z=8，ρ=1.2705 g·cm-3，μ=1.149 mm-1，F=1 997.5，R= 0.088 5，wR= 0.2229，GOF=1.035，I的热失重分析表明其在室温下是热稳定的。

关键词：水杨酸；苯并咪唑衍生物；锌配合物；晶体结构

中图分类号：TQ252.3　　文献标识码：A　　文章编号：1009-9212（2018）04-0030-05

Synthesis and Characterization of a Novel Derivative of Benzimidazole and Its Zinc Complex

LIU Hong1, XIE Bao-hua2 (1. School of Chemistry and Material Engineering, Huizhou university Guangdong, Huizhou 516007, China; 2. Finance Department, Huizhou university Guangdong, Huizhou 516007, China)

Abstract：2-(1-Octyl-1H-benzo[d]imidazole-2-yl)phenol(L) and its zinc complex(I) were prepared from salicylic acid, o-phenylenediamine and 1-bromooctane. Their structure and properties were characterized by IR, UV, 1H NMR, elemental analysis and so on. The luminescent properties of compound L and compound I were evaluated. Experimental data indicated that their maximum emission wavelength were 392 nm, 450 nm and 412 nm, respectively. The crystal structure of compound I was measured by X-ray single crystal diffraction and data analysis indicated that the compound I belonged to a monoclinic structure with a space group C2/c(a=30.424 4(15)?魡, b=9.794 4(4)?魡, c=17.896(1)?魡, V=5296.6(5)?魡3, Z=8, ρ=1.270 5 g·cm-3, μ=1.149 mm 1, F=199 7.5, R=0.088 5, wR=0.222 9, GOF=1.035). The thermogravimetic data analysis of compound I indicated that it was thermostable at room temperature.

Key words：salicylic acid; benzimidazole derivative; zinc complex; crystal structure

基金项目：惠州市科技局项目（2016ZX040），惠州学院校级项目（hzux1201415）。

作者简介：刘 鸿（1972-），男，江西新余人，讲师，主要从事精细有机合成和高分子合成的研究（E-mail：hzlh@hzu.edu.cn）。

收稿日期： 2018-08-0