第 50 卷第 1 期 Vol. 50 No. 1 2020 年 2 月 Feb 2020

所属栏目：安全与环保 碱解法降解抗蚜威废水中COD和抗蚜威的研究

干兴利1，2，秦岳军1，2，陈 灿1，2，张海涛1，2，曹金艳1，2 （1.湖南化工研究院有限公司 国家农药创制工程技术研究中心，湖南 长沙 410014；2.农用化学品湖南省重点实验室，湖南 长沙 410014）

摘　要：研究采用碱解法降解抗蚜威废水中的COD和抗蚜威。通过单因素试验考察了反应温度、初始反应pH值和保温反应时间等主要因素对废水中COD和抗蚜威去除率的影响。碱解法降解抗蚜威废水中COD和抗蚜威的优化条件：反应温度130℃，初始反应pH值为12、保温反应3 h，在此优化条件下，抗蚜威废水中COD的降解率为52.8%，抗蚜威的降解效果达到93.1%，BOD5／COD从0.03上升至0.42，废水可生化性得到大大提高。

关键词：碱解；废水；抗蚜威；降解率

中图分类号：X59　　文献标识码：A　　文章编号：1009-9212（2020）01-0070-03

Degradation of COD and Pirimicarb in Pirimicarb Wastewater by Alkaline Hydrolysis Process

GAN Xing-Li1,2, QIN Yue-Jun1,2, CHEN Can1,2, ZHANG Hai-Tao1,2, CAO Jin-Yan1,2 (1. National Enigineering Research Center for Agrochemicals, Hunan Chemical Research Institute Co.,Ltd., Changsha 410014, China; 2. Hunan Province Key Laboratory for Agrochemicals, Changsha 410014, China)

Abstract：The degradation of COD and Pirimicarb in Pirimicarb wastewater by alkaline hydrolysis process was studied in this paper. The effects of reaction temperature, initial reaction pH and heat insulation time on the removal of COD and pirimicarb in wastewater were investigated by single factor tests. Results showed that the optimum reaction conditions were as followings: reaction temperature of 130℃, pH value of 2, and heat insulation for 3 h, and the regredation rate, reaction efficiency and cost were also considered. Under the optimized conditions, the COD and Pirimicarb degradation rate were obtained as 52.8% and 93.1%, respectively, and BOD5/COD increased from 0.03 to 0.42 indicating that the biodegradability of wastewater was greatly improved.

Key words：alkaline hydrolysis; wastewater; Pirimicarb; degradation rate

基金项目：湖南省自然科学基金项目（2017JJ2079）。

作者简介：干兴利（1990-），男，湖南汨罗人，助理研究员，硕士研究生，主要从事废水处理与资源化利用（E-mail：625245791@qq.com）

收稿日期： 2020-01-2