| 第 51 卷第 1 期 |  | Vol. 51 No. 1 | | 2021 年 2 月 | Feb 2021 |
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所属栏目：农药及中间体
6-氯嘌呤类衍生物的合成及其诱导绿豆种子萌发活性 |
| 石凯强，周 繁，冉兆晋，毛志强，孙朝辉*
（中化集团 沈阳化工研究院有限公司，辽宁 沈阳 110021） |
| 摘 要：设计合成了一类具有高促生长活性和高水溶性的苯胺结构嘌呤类化合物12个，并对目标化合物进行了绿豆促萌发活性测试。目标化合物结构经1H NMR、MS确征。促进绿豆萌发活性测试结果表明：该类化合物对于促进绿豆萌发有较高活性；化合物3l在10 mg·L-1质量浓度下显示出较好的活性，促发芽率达到100%，化合物 3a和3c在1 mg·L-1质量浓度下的活性也优于阳性对照6-苄胺基嘌呤（6-BA）。化合物3l、3a、3c具有促进绿豆萌发的植物生长调节剂活性，为进一步研发高活性化合物奠定了基础。 |
| 关键词：植物生长调节剂；6-氯嘌呤类化合物；绿豆；促生长 |
| 中图分类号：TQ460.3 文献标识码：A 文章编号：1009-9212（2021）01-0008-03 |
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| Synthesis of 6-Chloropurine Derivatives and Its Activity of Germination Induction of Mung Bean |
| SHI Kai-qiang, ZHOU Fan, RAN Zhao-jin, MAO Zhi-qiang, SUN Chao-hui*
(Sinochem Shenyang Chemical Research Institute Co., Ltd., Shenyang 110021, China) |
| Abstract：To develop a purine compound with high growth promoting activity and high water solubility, a class of 12 purine compounds with aniline structure were designed and synthesized, and the target compounds were tested for the germination-promoting activity of mung bean. These target compounds were all characterized by 1H NMR and MS. The testing results of promoting the germination of mung bean showed that this kind of structure had certain activity in promoting the germination of mung bean; compound 3l showed good activity at a mass concentration of 10 mg·L-1 with the germination rate 100%; compounds 3a and 3c had better activity at a mass concentration of 1 mg·L-1 than the positive control 6-BA. As a result, compounds 3l, 3a, 3c had plant growth regulator activity for promoting the germination of mung bean to a certain extent, which laid the foundation for the further development of highly active compounds. |
| Key words：plant growth regulator; 6-chloropurine compounds; mung bean; growth promotion |
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作者简介：石凯强（1994—），男，山西大同人，硕士研究生，研究方向：有机合成。
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联 系 人：孙朝辉，教授级高级工程师，研究方向：染料、颜料及中间体，医药中间体。
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收稿日期：2021-02-24
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