| 第 32 卷第 6 期 |  | Vol. 32 No. 6 | | 2002 年 12 月 | Dec 2002 |
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所属栏目：其它
催化合成肉桂酸异戊酯 |
| 彭建兵; 银董红(湖南娄底师范高等专科学校化生系; 湖南师范大学精细催化合成研究所; 湖南娄底; 417000; 湖南长沙; 410081) |
| 摘 要：以苯甲醛为起始原料 ,经Perkin反应首先制备肉桂酸 ,然后在不同催化剂作用下经酯化反应合成了肉桂酸异戊酯 ,确定了最佳反应物的配料比、催化剂用量等反应条件 ,当对甲苯磺酸的用量为反应体系量的 3% ,酸醇比为 1∶1 3(mol)时 ,可得到 81%的肉桂酸异戊酯 ,并对合成产物的红外光谱和物理常数进行了测定 ,与文献值相符。 |
| 关键词：对甲苯磺酸; 肉桂酸; 异戊醇; 催化合成; 肉桂酸异戊酯 |
| 中图分类号：TQ224.4 文献标识码：A 文章编号：1009-9212(2002)06-0025-02 |
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| Catalytic Synthesis of Isoamyl Cinnamate |
| PENG Jian-hing; et al. （ Department of Chemistry and Biology; Hunan Loudi normalCollege; Hunan Loudi; 417000; China） |
| Abstract：The catalytic synthesis of isoamyl cinnamate by the esterifi-cation reaction of cinnamate acid and isoamylol in the presence of different acid catalysts was investigated in this paper. It was found that p-toluenesulfonic (PTS) acid was the efficient catalyst , and also the optimum conditions have been established from the ratio of reactants and the amount of catalyst used in the reaction. The yield of isoamyl cinnamate is 81% when the ratio of cinnamate acid and isoamylol was 1:1. 3, over 3% PTS catalyst. T... |
| Key words：phenyl-propenoate; isoamylol; isoamyl 3-phenyl-propenoate; p-toluenesulfonic; catalytic synthesis |
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基金项目：湖南省自然科学基金资助项目(01JJY3008)
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收稿日期：2002-08-16
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