第 52 卷第 6 期 Vol. 52 No. 6 2022 年 12 月 Dec 2022

所属栏目：表面活性剂 高双键保护率甲基封端烯丙醇聚醚的合成与反应活性研究

陈荧杰1，张美军2，金一丰3，张善炯2，张 静1 （1. 浙江绿科安化学有限公司，浙江 绍兴 312369；2. 浙江皇马尚宜新材料有限公司，浙江 绍兴 312369；3. 绍兴市特种表面活性剂新材料重点实验室，浙江 绍兴 312300）

摘　要：采用外循环式喷雾反应釜以烯丙醇聚醚、氢氧化钠溶液和氯甲烷为原料，合成得到甲基封端烯丙醇聚醚。对甲基封端烯丙醇聚醚合成工艺进行了优化，考察了醇盐化试剂、反应物配比、反应温度、反应时间等因素对反应的影响，优化条件下产品的双键保护率达98.3%，封端率达98.1%。并对产品进行反应活性研究，产品的硅氢化反应活性高，变清时间短，硅氢转化率达到98.4%。该合成工艺产品质量高、成本低，适合工业化生产。

关键词：烯丙醇聚醚；封端率；双键保护率；硅油改性剂

中图分类号：TQ326.5　　文献标识码：A　　文章编号：1009-9212（2022）06-0046-05

Synthesis and Reactivity of Methyl-terminated Allyl Polyethers with High Double Bond Retention

CHEN Ying-jie1, ZHANG Mei-jun2, JIN Yi-feng3, ZHANG Shan-jiong2, ZHANG Jing1 (1. Zhejiang Lukean Chemical Co., Ltd., Shaoxing 312369, China; 2. Zhejiang Huangma Shangyi New Material Co., Ltd., Shaoxing 312369, China; 3. Shaoxing Key Laboratory of New Materials for Special Surfactants, Shaoxing 312300, China)

Abstract：Methyl-terminated allyl polyether was obtained using allyl alcohol polyether, sodium hydroxide solution and chloromethane as raw materials, and an external circulating spray reactor was used. The synthesis process of methyl-terminated allyl polyether was optimized including alkylation reagent, reactant ratio, reaction temperature and reaction time. Under the optimized conditions, the double bond retention rate reached 98.3% and the sealing rate of the product reached 98.1%. The reactivity of the product was studied, and the product had high hydrosilylation activity, short cleaning time, and the silicon hydrogen conversion rate reached 98.4%. The product is of high quality and low cost, which is suitable for industrial production.

Key words：allyl alcohol polyether; sealing rate; double bond retention; silicone oil modifier

作者简介：陈荧杰（1988—），男，浙江上虞人，工程师，研究方向：表面活性剂的合成研究和产业化（E-mail：279507555@qq.com）。

收稿日期：2022-11-04