| 第 33 卷第 2 期 |  | Vol. 33 No. 2 | | 2003 年 4 月 | Apr 2003 |
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所属栏目：其它
SO_4~(2-)TiO_2固体超酸催化合成异丙基萘的研究 |
| 强敏; 林惠珊; 刘兴重; 柯昌美; 李莉(武汉科技大学; 湖北武汉; 430081) |
| 摘 要：用SO2 - 4 TiO2 固体超酸为催化剂合成了二异丙基萘 ,生产过程简单、无污染、无腐蚀。SO2 - 4 TiO2 固体超酸催化剂较为适宜的制备条件是 :浸酸浓度为 0 5 0mol/L、焙烧温度为 5 0 0℃。在催化剂用量为 10 %、反应温度为 160℃、反应时间为 2 5h的条件下连续两次使用SO2 - 4 TiO2 超酸催化萘对丙烯的烷基化反应 ,产品中一异丙基萘、二异丙基萘、三异丙基萘的总含量大于 98%。 |
| 关键词：萘; 丙烯; 异丙基萘; SO2-4TiO2; 固体超酸 |
| 中图分类号：TQ241.5 文献标识码：A 文章编号：1009-9212(2003)02-0022-02 |
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| Synthesis of Isopropylnaphthalene with SO_4~(2-)4TiO_2 Solid Superacid as Catalyst |
| QIANG Min etc.（Wuhan University of Science and Technology; Wuhan Hubei; 430081; China） |
| Abstract：SO 2- 4-TiO 2 solid superacid was used as catalyst in the alkylation of naphthalene with propylene to yield isopropylnaphthalene. The process is simple, lacking pollution and erosion. The optimal conditions of SO 2- 4-TiO 2 solid superacid are dipping acid concentration at 0.50?mol/L and calcinations temperature at 500?℃. The solid superacid can be used as catalyst two times in the alkylation of naphthalene, and the total composition of MIPN,DIPN, and TIPN in product is over 98%. When the consumpt... |
| Key words：naphthalene; propylene; isopropylnaphthalene; SO2-4-TiO2; solid superacid |
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收稿日期：2002-08-01
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