| 第 33 卷第 5 期 |  | Vol. 33 No. 5 | | 2003 年 10 月 | Oct 2003 |
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所属栏目：其它
2,4-二氯-3-乙基-6-硝基苯酚的合成 |
| 赵宏; 孙健; 张宏; 于滨; 秦学孔(中国科学院大连化学物理研究所国家催化工程技术研究中心; 辽宁大连) |
| 摘 要：介绍了以对硝基乙苯为原料 ,经三氯异氰脲酸氯化反应、碱解反应和酸化反应 ,高纯度 (大于 99% )、较高收率和较低成本地合成了目的产物的方法。该方法具有氯化试剂的投料量易于控制和反应控制简便等优点 |
| 关键词：2; 4-二氯-3-乙基-6-硝基苯酚; 显影剂; 有机合成; 三氯异氰脲酸; 氯化试剂 |
| 中图分类号：TQ243 文献标识码：A 文章编号：1009-9212(2003)05-0021-02 |
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| The Preparation of 2,4-Dichloro-3-ethyl-6-nitrophenol |
| ZHAO Hong; etc （National Engineering Research Center for Catalysis; Dalian Institute of Chemical Physics; The Chinese Academy of Sciences; Dalian Liaoling 116011; China） |
| Abstract：Dichloro-3-ethyl-6-nitrophenol which is the important intermediate to form developer in color photograph was prepared, using p-nitroethylbenzene as the start material .Through TCIA chlorination ,alkalization, and acidification reaction, the target product was gain with high purity(99%), high yield, and low costs. The amount of the chlorination agent charged into the reaction and preparation process can be controlled easily. |
| Key words：dichloro-3-ethyl-6-nitrophenol; color developer; organic synthesis; TCIA; chlorination agent |
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收稿日期：2003-05-23
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