| 第 34 卷第 2 期 |  | Vol. 34 No. 2 | | 2004 年 4 月 | Apr 2004 |
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所属栏目：其它
2,7-二甲氧基萘的合成 |
| 宋勇; 魏东升; 李向阳; 朱志庆(南通柏盛化工有限公司开发中心; 华东理工大学化工学院; 江苏启东) |
| 摘 要：以2,7 二羟基萘和硫酸二甲酯为原料,合成了2,7 二甲氧基萘。考察了各种因素对反应收率的影响,结果表明:当n(2,7 二羟基萘)∶n(硫酸二甲酯)=1∶3,反应温度80℃,w(NaOH)=48%,反应时间3h,采用滴加反应物硫酸二甲酯的加料方式,2,7 二甲氧基萘的收率可达到78 3%。 |
| 关键词：2; 7-二甲氧基萘; 7-二羟基萘; 硫酸二甲酯 |
| 中图分类号：O625.31+3 文献标识码：A 文章编号：1009-9212(2004)02-0035-02 |
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| The Synthesis of 2,7-Dimethoxynaphthalene |
| SONG Yong~1; WEI Dong-sheng~1; LI Xiang-yang~1; ZHU Zhi-qing~2 （1.Nantong Baisheng Chemical Co. Ltd.; Qudong 226236; China; 2.East China University of Science and Technology; Shanghai 200237; China） |
| Abstract：2,7-dimethoxynaphthalene was prepared from 2,7-dihydroxynaphthalene and dimethyl sulfate. The effects on the reaction were also discussed. Under the reaction conditions as follows: n(2,7-dihydroxynaphthalene0∶n(doimethylSulfate)=1∶3, reaction temperature of 80℃, reaction time of 3h and by means of dropwise of dimethylsulfate, the yield of 2,7-dimethoxynapthalene was up to 783%. |
| Key words：2; 7-dimethoxynaphthalene; 7-dihydroxynaphthalene; dimethylsulfate |
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收稿日期：2004-01-03
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