| 第 34 卷第 2 期 |  | Vol. 34 No. 2 | | 2004 年 4 月 | Apr 2004 |
|
所属栏目：其它
Reimer-Tiemann反应合成8-羟基喹啉-7-醛的研究 |
| 曾卓; 金利美; 焦小银; 郭灿城(湖南大学化学化工学院; 湖南长沙) |
| 摘 要：采用Reimer Tiemann反应合成杂环醛是一种简便易行的方法,在相转移催化剂AOT(2 乙基己基磺酸基琥珀酸钠)存在下,8 羟基喹啉通过Reimer Tiemann反应制备8 羟基喹啉 7 醛,该方法操作简单,收率较高且稳定,尚未见文献报道。 |
| 关键词：Reimer-Tiemann反应; 8-羟基喹啉-7-醛; AOT相转移催化剂 |
| 中图分类号：TQ253.23 文献标识码：A 文章编号：1009-9212(2004)02-0017-02 |
|
| Synthesis of 8-hydroxyquinoline-7-carboxaldehyde by Reimer-Tiemann reaction |
| ZENG Zhuo; JIN Li-mei; JUAI Xiao-yin; GUO Can-cheng （Institute of Chemistry and Chemical Engneering; Hunan University; Changsha 410082; China） |
| Abstract：The Reimer-Tiemann reaction is a convient and economical method for the synthesis of heteroaldehyde. The 8-hydroxyquinoline-7-carboxaldehyde was synthesized by 8-hydroxyquinoline through Reimer-Tiemann reaction in the presence of the phase-transfer catalyst AOT. The yield is high and stable. |
| Key words：Reimer-Tiemann reaction; 8-hydroxyquinoline-7-carboxaldehyde; phase-transfer catalyst AOT |
|
收稿日期：2004-03-11
|
| 阅读全文 |
|