| 第 34 卷第 3 期 |  | Vol. 34 No. 3 | | 2004 年 6 月 | Jun 2004 |
|
所属栏目：其它
新法合成邻苯二甲酰亚胺 |
| 岳海艳; 刘占峰(辽宁工学院材化系; 北京化工大学化学工程学院; 辽宁锦州) |
| 摘 要：以苯酐和尿素为原料,邻二甲苯为溶剂,通过优化操作,探索出合成邻苯二甲酰亚胺优惠工艺条件:苯酐:尿素:溶剂(摩尔比)=1:0.6:3,反应时间90min,反应温度144℃,产品的收率最高可达到99%(以苯酐计),溶剂可重复使用。 |
| 关键词：苯酐; 尿素; 溶剂; 邻苯二甲酰亚胺 |
| 中图分类号：TQ245.2 文献标识码：A 文章编号：1009-9212(2004)03-0044-02 |
|
| A New Synthetic Process of Phthalimide |
| YUE Hai-yan~1; LIU Zhan-feng~2 （1.Department of material and chemistry; Liaoning Institute of Technology; Jinzhou 121000; China; 2. Institute of Chemical Engineering; Beijing University of Chemical Technology; Beijing 100029; China） |
| Abstract：The phthalimide has been synthesized from phthalic anhydride and urea in ortho-xylene solvent medium. In the process, ortho-xylene which plays a role as solvent can be used repeatedly. The optimum condition of the proposed method involves:interaction at 144 ℃,for 90 minutes and in the mole ratio phthalic anhydride∶urea∶ortho-xylene=1.0∶0.6∶3.0, the highest yield of phthalimide has achieved 99 %. |
| Key words：phthalic anhydride; urea; solvent; phthalimide |
|
收稿日期：2004-02-22
|
| 阅读全文 |
|