| 第 34 卷第 4 期 |  | Vol. 34 No. 4 | | 2004 年 8 月 | Aug 2004 |
|
所属栏目：其它
粗异戊烯的醚化 |
| 范存良; 唐豪; 王世明(上海石油化工股份有限公司化工研究所) |
| 摘 要：研究了苯磺酸型树脂催化的异戊烯和甲醇的醚化,考查了温度、醇烯比和空速对反应的影响。结果表明在反应温度为59～67℃、甲醇与异戊烯的摩尔比值为1 4～1 6、液时空速为1 1～1 5h-1时反应的转化率大于70%。 |
| 关键词：醚化; 异戊烯; 甲基叔戊基醚 |
| 中图分类号：TQ223.2+4 文献标识码：A 文章编号：1009-9212(2004)04-0047-02 |
|
| The Etherification of Crude Isoamylenes |
| FAN Cun-liang; TANG Hao; WANG Shi-ming （Shanghai Petrochemical Company Limited; Shanghai 200540; China） |
| Abstract：The etherification of isoamylenes and methanol to form tert ayl methyl ether (TAME) by benzl-sulfonic acid cation exchange resin as catalyst, was sudied. The influences of temperature, methanol/isoamylenes ratio and LHSV have been investigated. The results indicats that the resin is an effective catalyst with conversion over 70% at 59～67?℃ and n(methanol)∶n(isoamylenes)=1.4～1.6∶1.0,LHSV=1.1～1.5. |
| Key words：etherification; isoamylenes; tert-ayl methyl ether |
|
收稿日期：2003-11-14
|
| 阅读全文 |
|