| 第 34 卷第 6 期 |  | Vol. 34 No. 6 | | 2004 年 12 月 | Dec 2004 |
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所属栏目：其它
西藏麝香合成新工艺 |
| 王玉芳; 刘杰; 刘岗(锦州石化公司; 锦州石化精细化工有限公司; 辽宁锦州) |
| 摘 要：以催化重整C9芳烃分离装置分离出均三甲苯、偏三甲苯后的副产品重组分溶剂(169～178℃馏分)—混合C9芳烃为原料,其中含连三甲苯40%～50%,以三氯化铝为催化剂与异丁烯进行烷基化反应,合成出5 叔丁基 1,2,3 三甲基苯中间体,经蒸馏后,用混酸进行硝化反应得到西藏麝香。本方法不但具有工艺路线简单,生产成本低的特点,同时也解决了富集连三甲苯的利用问题。 |
| 关键词：西藏麝香; C9芳烃; 异丁烯 |
| 中图分类号：TQ246.1 文献标识码：A 文章编号：1009-9212(2004)06-0037-02 |
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| A new Process for Synthesis of Musk Tibetene |
| WANG Yu-fang~1; LIU Jie~2; LIU Gang~2 （1.Jinzhou Petrochemical Co.; Jinzhou 121001; China; 2.Jinzhou Petrochemical-finechemical Co.Ltd.; China） |
| Abstract：In this process , the heavy fraction solvent (169～178℃)— mixed C_(9) aromatic hydrocarbon, namely, the by-product of mesitylene and pseudocumene which were separated from C_(9) aromatic hydrocarbon catalytic reforming separation facility , will be the feedstock which was alkylated by isobutene in presence of aluminium trichloride as catalyst to synthesize 5-tert-butyl-1,2,3 trimethyl benzene intermediate product which , after distillation ,was nitrated with nitro-sulfuric acid to obtain Musk Tibetene. This ... |
| Key words：Musk Tibetene; C_（9） aromatic hydrocarbon; isobutene |
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收稿日期：2004-06-25
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