第 35 卷第 2 期 Vol. 35 No. 2 2005 年 4 月 Apr 2005

所属栏目：专论与综述 超临界流体在有机合成中的应用新进展

张现斌; 梁发书; 邹长军(西南石油学院化学化工学院; 四川成都)

摘　要：综述了超临界流体应用于有机合成的新成果及新动向,包括催化氢化、Diels-Alder反应、烯键易位反应、环化反应、费托合成、傅克烷基化反应、酯化反应、氧化反应、烷基化反应、重排反应和水解反应等方面。它在绿色化学反应方面具有很大的潜在优势。

关键词：超临界流体; 有机合成; 绿色化学反应

中图分类号：TQ028.32　　文献标识码：A　　文章编号：1009-9212(2005)02-0001-05

The Review of Organic Synthesis under Supercritical Condition

ZHANG Xian-bin; LIANG Fa-shu; ZOU Chang-jun （College of Chemistry and Chemical Engineering; Southwest Petroleum Institute; Chengdu 610500; China）

Abstract：The recent achievements in application of supercritical fluids, as a new reaction system in organic synthesis ,such as catalytic hydrogenation, Diels-Alder reaction, cyclic reaction, Fischer-Tropsch reaction, Friedel-Crafts reaction, esterification, oxidation, alkylation, arrangement, hydrolysis etc. were reviewed. Many references of latest ten years were covered. It has great potential application in green chemical reaction.

Key words：supercritical fluids; organic synthesis; green chemical reaction

基金项目：四川省重点实验室项目(S0005)

收稿日期：2004-11-26

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