| 第 35 卷第 4 期 |  | Vol. 35 No. 4 | | 2005 年 8 月 | Aug 2005 |
|
所属栏目：染料、颜料及涂料
铜酞菁聚甲基丙烯酸甲酯的合成与表征 |
| 邓建成; 殷焕顺; 周燕; 张海良(湘潭大学化学学院; 湖南湘潭) |
| 摘 要：以氯甲基化铜酞菁为引发剂,过渡金属卤化物和配位剂(Cu2Cl2/2,2`-联吡啶)为催化体系,进行甲基丙烯酸甲酯原子转移自由基聚合反应,合成出了铜酞菁聚甲基丙烯酸甲酯,并对其进行了结构表征。 |
| 关键词：铜酞菁; 氯甲基化; 原子转移自由基聚合 |
| 中图分类号：TQ225.24 文献标识码：A 文章编号：1009-9212(2005)04-0039-03 |
|
| Synthesis and Characterization of Copper Phthalocyanine-end-capped poly [Methyl methacrylate] |
| DENG Jian-cheng; YIN Huan-shun; ZHOU Yan; ZHANG Hai-liang （College of chemistry of Xiangtan University; Xiangtan 411105; China） |
| Abstract：A novel copper phthalocyanine-end-capped poly[methyl methacrylate] was synthesized by atom transfer radical polymerization (ATRP) using chloromethylate copper phthalocyanine as an initiator and CuBr/2,2-bipydrine as a catalyst. The structure and molecular weight of the copper phthalocyanine PMMA was confirmed by GPC, IR and UV/VIS spectrum. |
| Key words：Copper phthalocyanine-end-capped poly[Methyl methacrylate]; chloromethylation; atom transfer radical polymerization |
|
收稿日期：2005-03-02
|
| 阅读全文 |
|