| 第 35 卷第 4 期 |  | Vol. 35 No. 4 | | 2005 年 8 月 | Aug 2005 |
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所属栏目：专论与综述
乙苯催化氧化合成苯乙酮研究进展 |
| 李家其; 郭军; 尹笃林(湖南师范大学化学化工学院; 湖南人文科技学院化学系; 湖南长沙410081湖南人文科技学院化学系; 湖南娄底; 湖南长沙) |
| 摘 要：综述了乙苯催化氧化合成苯乙酮的研究进展,介绍了杂多化合物、过渡金属络合物、金属原子簇化合物、金属卟啉化合物及分子筛催化剂对乙苯选择氧化反应的催化效果和特点。结果表明,钼钒磷杂多化合物及钴络合物是乙苯催化氧化反应的理想催化剂,具有良好的应用前景。 |
| 关键词：乙苯; 催化; 氧化; 苯乙酮 |
| 中图分类号：TQ244 文献标识码：A 文章编号：1009-9212(2005)04-0001-03 |
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| Progress on Ethylbenzene Catalytic Oxidation to Synthesize Acetophenone |
| LI Jia-qi1; 2; GUO Jun 2; YIN Du-lin （1.College of Chemistry and Chemical Engineering; Hunan Normal University; Changsha 410081; China; 2.Department of chemistry; Hunan Humanities Science and Technology College; Loudi 417000; China） |
| Abstract：The research development on behaviors of ethylbenzene catalytic oxidation to synthesize acetophenone was reviewed.The functions and characteristic of catalysts in selective oxidation of ethylbenzene were described for heteropoly compound, transition metal complex, transition metal compound, metal cluster compound,metalloporphyrin compound and molecular sieve catalyst.The results showed that the molybdovanado phosphate heteropoly compound and cobalt complex were good catalysts for the catalytic oxidation of ... |
| Key words：ethylbenzene; catalyst; oxidition; acetophenone |
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收稿日期：2005-03-22
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