| 第 35 卷第 5 期 |  | Vol. 35 No. 5 | | 2005 年 10 月 | Oct 2005 |
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所属栏目：染料、颜料及涂料
硝基萘磺酸催化加氢生产周位酸工艺研究 |
| 朱仁发; 俞汉青; 杨家仁; 江鹏程(中国科学技术大学化学系; 铜化集团有机化工有限责任公司; 安徽合肥; 安徽铜陵) |
| 摘 要：在研究了现有生产硝基萘磺酸还原生产周位酸工艺的基础上,采用绿色新工艺,利用 自制的混合催化剂,对影响反应的各种因素进行了研究,并通过实验选定了优化工艺条件。实验结 果表明,在温度95℃,催化剂用量为硝基物质量的O．5％,反应时间为5h左右。产物收率在98％ 以上(以总氨基值计),还原率为99％以上。 |
| 关键词：硝基萘磺酸; 周位酸; 催化加氢 |
| 中图分类号：TQ612.3 文献标识码：A 文章编号：1009-9212(2005)05-0030-02 |
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| Study on the Catalytic Hydrogenation in the Preparation of Peri Acid from Nitronaphthalenesulfonic Acid with Hydrogen |
| ZHU Ren-fa; YU Han-qing; YANG Jia-ren; JIANG Peng-cheng Department of Chemistry; USTC; Hefei 230026; China; Organic Chemistry Industry Limited Company; TLCIG; Tongling 244027 |
| Abstract：The peri acid (Laurent' acid) was synthesized from nitronaphthalenesulfonic acid by mixed catalyst made by laboratory, and the novel green catalytic hydrogenation technology in the preparation of periacid was adopted. The factors that influenced the reaction conditions were studied, and the proper technological parameters were ascertained by experiments. The results showed that the ratio of catalyst to the main reactants was 0.5%, the reaction temperature was 95℃, and reaction time was 5 h. Under those cond... |
| Key words：nitronaphthalenesulfonic acid; peri acid; catalytic hydrogenation |
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收稿日期：2005-07-12
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