| 第 35 卷第 6 期 |  | Vol. 35 No. 6 | | 2005 年 12 月 | Dec 2005 |
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所属栏目：医药及中间体
芳维A酸糖酯的合成与结构表征 |
| 党奎峰; 陈超越; 殷小秋; 尹凯; 向建南(湖南大学化学化工学院; 湖南大学医院; 湖南长沙; 安徽理工大学化学工程系; 安徽淮南) |
| 摘 要：在碳酸钠和四丁基溴化铵催化下,将芳维A酸分别与O-乙酰基溴代葡萄糖、O-乙酰基溴代木糖、O-乙酰基溴代乳糖、O-乙酰基溴代麦芽糖作用,制得相应的芳维A酸乙酰基糖酯。并以IR、MS1、HNMR确认了4个糖酯的结构。 |
| 关键词：芳维A酸; 糖酯; 合成; 表征 |
| 中图分类号：O62 文献标识码：A 文章编号：1009-9212(2005)06-0032-03 |
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| Synthesis and Characterization of Glycosyl Esters Derivatives of all-trans-Aritinoic acid |
| DANG Kui-feng;CHEN Chao-yue;Yin Xiao-qiu;Yin Kai;XIANG Jian-nan(College of Chemistry and Chemical Engineering;Hospital of Hunan Univ.Changsha;Department of Chemical Engineering;Anhui University of Science and Technology) |
| Abstract：Four new glucosyl esters of all-trans-aritinoic acid were synthesized by the reaction of all-trans-aritinoic acid with O-acetylglucopyranosyl bromide or O-acetylgalactopyranosyl bromide,O-acetylgalactopyranosyl bromide,O-acetylgalactopyranosyl bromide in the presence of sodium carbonate and Bu4NBr.Their structures were confirmed by IR?1H NMR and MS. |
| Key words：all-trans-aritinoic acid; glycosyl esters; synthesis; characterization |
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基金项目：教育部留学归国人员基金(No.2003406);国家自然科学基金(No.20472018);湖南省自然科学基金(No.03JJY3016)
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收稿日期：2005-09-25
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