| 第 35 卷第 6 期 |  | Vol. 35 No. 6 | | 2005 年 12 月 | Dec 2005 |
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所属栏目：专论与综述
二氯化苯基膦的合成进展 |
| 谢文杰; 王鉴; 曾群; 曲云龙; 杨年兴(大庆石油学院化学化工学院; 天津大学化工学院; 大庆石化公司; 黑龙江大庆) |
| 摘 要：简要的介绍了苯基二氯化磷的用途及发展前景,综述了苯基二氯化磷的合成方法。着重从催化机理和反应历程的角度探讨了三氯化铝催化合成DCPP、离子液体催化合成DCPP、自由基加成反应合成DCPP三类合成反应的过程,并综述了各类反应的进展情况及存在的问题。寻找一条绿色无污染,工艺简单,操作容易,收率高的合成路线,仍然是该领域的热门课题。 |
| 关键词：二氯化苯基膦; 合成机理; 中间体 |
| 中图分类号：TQ265.1 文献标识码：A 文章编号：1009-9212(2005)06-0019-03 |
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| Development of the Synthesis of Dichlorophenylphosphine |
| XIE Wen-jie;WANG Jian;ZENG Qun;QUN Yun-long;YANG Nian-xing(Chemistry and Chemical Engineering College;Daqing Petraleum Institute;Daqing 163318;China;Chemical Engineering College;Tianjin University;Tianjin;Daqing Chemical Company SINOPEC; China) |
| Abstract：The application and prospect of dichlorophenylphosphine dichloride were briefly introduced,and the synthetic method of dichlorophenylphosphine dichloride was also described.The processes of preparing DCPP through AlCl3 catalytic synthesis?ionic liquid catalytic synthesis?free radical addition reaction synthesis,were discussed mainly in aspect of the mechanism of catalytic reaction,the existing problems and the progress of the study on the reaction were also discussed.Finding a new simple synthetic process w... |
| Key words：dichlorophenylphosphine; mechanisms of the reaction; intermediate |
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收稿日期：2005-09-21
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