| 第 36 卷第 1 期 |  | Vol. 36 No. 1 | | 2006 年 2 月 | Feb 2006 |
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所属栏目：农药及中间体
1-苄基-5-苯基-1,2,3-三氮唑的合成 |
| 刘瑛; 黄华伟(河南商邱师范学院化学系; 河南商邱) |
| 摘 要：以氯化苄和叠氮化钠为原料,通过叠氮化反应,制得叠氮苄,反应收率达到95.2%。苯乙炔和叠氮苄,通过1,3-偶极环加成反应制得1-苄基-5-苯基-1,2,3-三氮唑,收率26%。该反应是原子经济的绿色化学反应。 |
| 关键词：叠氮苄; 1; 3-偶极环加成反应; 2; 3-三氮唑; 合成 |
| 中图分类号：TQ252.6 文献标识码：A 文章编号：1009-9212(2006)01-0030-02 |
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| Synthesis of 1-Benzyl-5-phenyl-1,2,3-triazole |
| LIU Ying; HUANG Hua-wei（Department of Chemistry; Shangqiu Normal University; Shangqiu 476000; China） |
| Abstract：Benzylazide was synthesized via the reaction of benzyl chloride with sodium azide,and its yield was 95.2%,1-Benzyl-5-phenyl-1,2,3-triazole was prepared through 1,3-dipolar cycloaddition reaction with benzylazide and phenylacetylene,and the yield was 26%.The reaction is atom economic green chemistry reaction. |
| Key words：benzylazide; 1; 3-dipolar cycloaddition reaction; 2; 3-triazole; synthesis |
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收稿日期：2005-09-23
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