第 36 卷第 3 期 Vol. 36 No. 3 2006 年 6 月 Jun 2006

所属栏目：分析与测试 Ziegler-Natta催化剂催化的1-癸烯齐聚物的结构表征

阳小宇(湖南化工职业技术学院; 湖南株洲)

摘　要：采用GC-MS和13C NMR对Ziegler-Natta催化剂催化1-癸烯齐聚所得齐聚物的组成和结构进行了表征。GC-MS和GC的分析结果表明所得齐聚物是混合物,主要由二聚体、三聚体、四聚体和五聚体组成。齐聚物的质量百分含量分别为14%、45%、31%和10%。13C NMR结果表明1-癸烯齐聚时存在键接异构,除头-尾键接的1,2插入,还存在头-头,尾-尾键接的2,1插入。1-癸烯齐聚物的倾点低,粘度指数高。

关键词：1-癸烯; 齐聚物; 结构; 性能

中图分类号：TQ314.258　　文献标识码：A　　文章编号：1009-9212(2006)03-0067-03

Structure and Properties of Oligomer from 1-Decene Catalyzed by Ziegler-Natta Catalyst

YANG Xiao-yu（Hunan Chemical Industry Profession and Technology College; Zhuzhou 412004; China）

Abstract：The oligomer from 1-decene promoted by Ziegler-Natta Catalyst was characterized with GC-MS,GC and 13C NMR methods.The results from GC-MS and GC analysis confirmed that the oligomer was a mixture consisting of di-(14%),tri-(45%),tetra-(31%) and pentamer(10%).The 13C NMR data also implied that the chain propagation of the oligomer involved primarily head-to-tail 1,2-insertions,as well as head-to-head and tail-to-tail 2,1-insertions.The oligomer obtained featured lower pour point and high viscosity index.

Key words：1-decene; oligomer; structure; properties

收稿日期：2006-02-19

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