| 第 36 卷第 4 期 |  | Vol. 36 No. 4 | | 2006 年 8 月 | Aug 2006 |
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所属栏目：香精香料
超声波引发格氏反应制备几种香料 |
| 袁金亮; 甄宏爝(广州道明化学有限公司; 广州百花香料股份有限公司; 广东广州) |
| 摘 要：以超声波为引发条件,引发制备格氏试剂,从而制备几种香料:二甲基苄基原醇、4-甲基-3-癸烯-5-醇、1-辛烯-3-醇、8-烯丙基-8-羟基三环[5,2,1,02,6]癸烷。与常规引发条件相比,超声波引发格氏反应具有反应时间短、节约能源、操作简便、收率高等优点。 |
| 关键词：合成; 超声波; 格氏反应; 香料 |
| 中图分类号：TQ655 文献标识码：A 文章编号：1009-9212(2006)04-0037-03 |
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| Synthesis of Aromatics by Grignard Reaction with Supersonic Wave as Revulsant |
| YUAN Jin-liang1; ZHEN Hong-jue2（1. Guangzhou Daoming Chemical Co.; Ltd.; Guangzhou 510665; China; 2 . Guangzhou Baihua Flavors & Fragrances Co.; Guangzhou 510370; China） |
| Abstract：Synthesis methods of some aromatics such as dimethylbenzyl carbinol,4-methyl-3-decene-5-ol,1-octene-3-ol,8-allyl-8-hydroxytricyclo[5,2,1,02,6]decane by Grignard reaction were summarized in the paper using supersonic wave as revulsant. This method had characteristics of short reaction time,few energetic resources,simple operation conditions,high yield,and etc compared with the conventional methods. |
| Key words：supersonic wave; Grignard reaction; aromatics; synthesis |
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收稿日期：2006-03-06
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