| 第 36 卷第 5 期 |  | Vol. 36 No. 5 | | 2006 年 10 月 | Oct 2006 |
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所属栏目：农药及中间体
5-降冰片烯-2-醛的合成研究 |
| 王彦丽; 高中良; 赵连营; 刘雁(河北工业大学化工学院) |
| 摘 要：2-氯-5-氯甲基吡啶是生产吡虫啉、吡虫清和噻虫啉等的重要中间体,5-降冰片烯-2-醛是环戊二烯-丙稀醛法合成2-氯-5-氯甲基吡啶第一步反应中得到的中间产物。5-降冰片烯-2-醛由环戊二烯和丙稀醛发生狄尔斯-阿尔德(Diels-Alder)反应而成。以正交实验方式优化出5-降冰片烯-2-醛的反应条件。考查了原料配比、反应温度和反应时间对反应的影响,并对不同的保温温度进行考查,确定出最佳的保温温度。 |
| 关键词：除草剂; 三氟啶磺隆; 2-巯基-3-苄氧基吡啶; 2-氯-3-羟基吡啶 |
| 中图分类号：TQ224.15 文献标识码：A 文章编号：1009-9212(2006)05-0054-03 |
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| Synthesis of 5-Norbornene-2-carboxaldehyde |
| WANG Yan-li; GAO Zhong-liang; ZHAO Lian-ying; LIU Yan（College of Chemical Enginering; Hebei University of Technology; Tianjin 300130; China） |
| Abstract：2-Chloro-5-chloromethylpyridine was known as an important intermediate of insecticide such as imidacloprid,acetamiprid and thiacloprid.5-Norbornene-2-carboxaldehyde was the first intermediate of 2-chloro-5-chloromethylpyridine synthesized through dicyclopentadiene-acrylic aldehyde method.5-Norbornene-2-carboxaldehyde was prepared by acrylic aldehyde and dicyclopentadiene,the optimum reaction conditions were obtained via orthogonal experiments.The effect of the proportion of raw materials,the reaction temper... |
| Key words：dicyclopentadiene; acrylicaldehyde; 5-norbornene-2-carboxaldehyde |
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收稿日期：2006-07-10
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