| 第 36 卷第 6 期 |  | Vol. 36 No. 6 | | 2006 年 12 月 | Dec 2006 |
|
所属栏目：功能材料
丙烯酸-丙烯酰胺高吸水树脂溶液共聚与吸液性能研究 |
| 刘新容; 谢建军; 梁吉福(湘潭大学化学学院; 中南林业科技大学材料科学与工程学院流变力学与材料工程研究所; 湖南湘潭; 湖南长沙) |
| 摘 要：以丙烯酸(AA)和丙烯酰胺(AM)为原料,过硫酸钾为引发剂,N,N-亚甲基双丙烯酰胺为交联剂,采用水溶液聚合对丙烯酸-丙烯酸胺(PAAAM)高吸水树脂的合成条件进行了优化。结果表明,在室温下最大吸蒸馏水倍率为2710g/g,在w(NaCl)=0.9%的水溶液中吸水倍率为133g/g。考察了单体质量分数、交联剂质量分数以及引发剂质量分数对PAAAM在蒸馏水及w(NaCl)=0.9%溶液中吸液性能的影响,并对实验结果进行了回归分析。 |
| 关键词：高吸水树脂; 丙烯酸; 丙烯酰胺; 吸水倍率; 溶液聚合 |
| 中图分类号：TQ325.7 文献标识码：A 文章编号：1009-9212(2006)06-0056-05 |
|
| Preparation and Absorbency of Acrylic Acid-Acrylamide Superabsorbents by Solution Polymerization |
| LIU Xin-rong;XIE Jian-jun;LIANG Ji-fu(Institute of Polymer Materials;Xiangtan University;College of Materials Science and Engineering;Institute of Rheology and Materials Engineering;Central South Forestry University and Technology) |
| Abstract：Some superabsorbents(PAAAM)were prepared from copolymer of part-neutralized acrylic acid(AA)and acrylamide(AM) with potassium peroxydisulfate as initiator,N,N'-methylene-bis-acrylamide as crosslinking agent,by means of water solution polymerization.The polymerization conditions were optimized by orthogonal experiment method and single factor experiment method,and the absorbencies of PAAAM in distilled water and 0.9% NaCl solutions were regression-analyzed.The maximum absorbency of the superabsorbent in dist... |
| Key words：superabsorbent; acrylic acid; acrylamide; absorbency; solution polymerization |
|
基金项目：湖南省科技攻关计划资助项目(05NK3052);中南林业科技大学人才启动基金项目
|
收稿日期：2006-06-14
|
| 阅读全文 |
|